(Norbornadien) molibden tetrakarbonil - (Norbornadiene)molybdenum tetracarbonyl

(Norbornadien) molibden tetrakarbonil
Mo (nbd) (CO) 4.png
Mo (nbd) (CO) 4 namuna (spatula bilan) .jpg
Identifikatorlar
3D model (JSmol )
ChemSpider
ECHA ma'lumot kartasi100.151.941 Buni Vikidatada tahrirlash
Xususiyatlari
C11H8MoO4
Molyar massa300.13 g · mol−1
Xavf
GHS piktogrammalariGHS07: zararli
GHS signal so'ziOgohlantirish
H302, H312, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301 + 312, P302 + 352, P304 + 312, P304 + 340, P305 + 351 + 338, P312, P321, P322, P330, P332 + 313, P337 + 313, P362, P363, P403 + 233, P405, P501
Boshqacha ko'rsatilmagan hollar bundan mustasno, ulardagi materiallar uchun ma'lumotlar berilgan standart holat (25 ° C [77 ° F], 100 kPa da).
Infobox ma'lumotnomalari


(Norbornadien) molibden tetrakarbonil bo'ladi organomolibden birikmasi formula bilan (C7H9) Mo (CO)4. Tarkibiy jihatdan, birikma quyidagilardan iborat norbornadien Mo (CO) ga bog'langan4 parcha Murakkab sariq, uchuvchan qattiq moddadir. U termik yoki fotokimyoviy almashtirish bilan tayyorlanadi molibden geksakarbonil.[1] Murakkab dastlab potentsial sifatida o'rganilgan qulfdan chiqarish agenti.[2]

(Norbornadien) molibden tetrakarbonil L tipidagi boshqa hosilalarning kashshofidir.2Mo (CO)4. Ushbu konversiya dien ligandining labilligidan foydalanadi:[3]

(C7H9) Mo (CO)4 + 2 L → C7H9 + L2Mo (CO)4

Adabiyotlar

  1. ^ Verner, Helmut; Prinz, Richard (1967). "Ein neuer Weg zur Darstellung substituierter Metallcarbonyl ‐ Komplekse von Chrom und Molybdän". Chemische Berichte. 100: 265–270. doi:10.1002 / cber.19671000131.
  2. ^ US3093671, Ihrman, Krin G.; Coffield, Thomas H., "Tsiklik dienli metal karbonil komplekslari" 
  3. ^ Xann, F. Ekkehardt; Wittenbecher, Lars; Le Van, Dyuk; Fruhlich, Roland (2000). "N-geterosiklik karben va uning eritmasidagi dimer o'rtasidagi muvozanatning dalillari". Angewandte Chemie International Edition. 39 (3): 541–544. doi:10.1002 / (SICI) 1521-3773 (20000204) 39: 3 <541 :: AID-ANIE541> 3.0.CO; 2-B.