Uglerod nitridi - Carbon nitride

Siyanogen uglerod nitrididir.

Uglerod nitridlari uglerod va azot birikmalaridir.

Kovalent tarmoq birikmalari

Azafullerenes

  • Azafullerenes sinfidir heterofullerenes unda uglerod o'rnini bosuvchi element azotdir.[2] Bunga misollar (C59N)2 (biazafullerenil),[3] C58N2 (diaza [60] fullerene), S57N3 (triaza [60] fullerene) va C48N12.

Siyanofullerenlar

  • Siyanofullerenlar o'zgartirilgan sinf fullerenlar unda siyanogruplar fulleren skeletiga biriktirilgan. Ular C formulasiga ega60(CN)2n, bu erda n 1 dan 9 gacha bo'lgan qiymatlarni oladi.

Siyanogen

Percyanoalkynes, -alkenes va -alkanlar

  • ditsanoatsetilen - C4N2 [C2(CN)2], shuningdek uglerod subnitrid yoki but-2-ynedinitril deb ham ataladi
  • tetratsyanoetilen - C6N4 [C2(CN)4]
  • tetratsyanometan - C5N4 [C (CN)4]
    • 2,2-diizosiyanopropanedinitril - C5N4 [C (CN)2(Bosimining ko'tarilishi)2]
  • geksasiyanoetan - S8N6 [C2(CN)6]
  • geksatsianotsiklopropan - S9N6 [C3(CN)6]
  • geksasyanobutadien[4] - C10N6 [C4(CN)6]

Dicanopolyynes

Ditsianopolyinlar azot atomlari bilan tugaydigan, o'zgaruvchan bitta va uch karra bog'langan uglerod atomlari zanjiridan iborat. Garchi poliin ditsanoatsetilen ushbu qatorga mos kelmasa ham.

  • ditsianobutadiyne (ditsianodiatsetilen) - C6N2
  • dicyanohexatriyne - C8N2
  • C10N2
  • C12N2
  • C14N2
  • C16N2
  • C18N2
  • C20N2
  • C22N2

Perazidoalkinlar, -alkenlar va -alkanlar

Persiyanogeterotsikllar

Aromatik siyanokarbonatlar

  • geksasiyanenzol - S12N6
  • oktatsianonaftalik - C18N8
  • dekatsiyanoantrasen - S24N10

Boshqa birikmalar

  • siyanitren - CN2 [NCN]
  • azodikarbonitril - S2N4 [(NCN)2]
  • siyanogen azid - CN4 [NC.N3]
  • 1-diazidokarbamoyl-5-azidotetrazol - C2N14
  • triazidotriazin (siyanurik triazid) - C3N12 [C3N3(N3)3]
  • triazidoheptazin - S6N16 [C6N7(N3)3]
  • tricyanomethanimine (Dicyanomethylene-siyanamid) - C4N4 [(CN) .N.C (CN)2]
  • diazidoditsianoetilen - S4N8 [(N3)2.C.C (CN)2]
  • ditsianodiazometan - C3N4 [(CN)2.C.N2]
  • ditsianokarben - C3N2 (va siyanoizosiyanokarben, diizosiyanokarben, 3-siyano-2H-azireniliden va 3-izosiyano-2H-azireniliden izomerlari)
  • 1,3,5-triazido-2,4,6-tricyanobenzol - S9N12 [C6(CN)3(N3)3]
  • azot tricyanide N (CN)3 va uglerod bis (siyanamid) NCN = C = NCN, polimer C ning ikki rasmiy monomeri3N4

Anionlar

  • siyanid va izosiyanid - CN− va bosimining ko'tarilishi−
  • ditsanamid - N (CN)2−
  • tricyanometanid - C (CN)3−
  • pentatsiyanoetanid - C2(CN)5−
  • pentatsyanopropenid (pentatsyanoallil anion) - C3(CN)5−
  • 2-ditsianometilen-1,1,3,3-tetratsyanopropanediid S10N62− [(C (C (CN))2)32−]
  • tricyanomelaminate anion - C3N3(NCN)3]3−
  • qovun - C6N7(NCN)3]3−
  • siyanofulleren anionlari - C60(CN)n− (n toq) va C60(CN)n2− (n hatto)
  • siyanopolinid anionlari - CnN− (n g'alati)
    • siyanoatsetidid - C3N−
    • siyanobutadiynilid - C5N−

Shuningdek qarang

Adabiyotlar

  1. ^ Lv, Hongying; Teng, Zhenyuan; Vang, Sicong; Feng, Ke; Vang, Syaoli; Vang, Chengin; Vang, Guoxiu (mart 2018). "Guruch ildizi yuzasi yonida Cu2 +, Pb2 + va Hg2 + uchun voltammetrik bir vaqtning o'zida ion oqimini o'lchash platformasi: Uglerod nitridli heterojunksiyali plyonkadan modifikatsiyalangan uglerod tolasi mikroelektridan foydalanish". Datchiklar va aktuatorlar B: kimyoviy. 256: 98–106. doi:10.1016 / j.snb.2017.10.053.
  2. ^ D.J. Harris, nitroballs kashfiyoti: Fulleren kimyosi bo'yicha tadqiqotlar, 1993 yil Kaliforniya shtatidagi ilmiy ko'rgazma, http://www.usc.edu/CSSF/History/1993/S05.html
  3. ^ Hummelen va boshq., Geterofullerene C59N ni uning dimeri sifatida ajratish (C59N) 2, Science 269: 1554-1556 (1995)
  4. ^ OW Vebster, Geksatsyanobutadien, J. Am. Kimyoviy. Soc. 86 (14): 2898-2902 (1964)
  5. ^ a b Sesto va boshq., 2,4,6-Tricyano-1,3,5-triazin va 1,3,5-Tricyanobenzolni kimyoviy kamaytirish. 4,4 ', 6,6'-Tetracyano-2,2'-bitriazin va uning radikal anioni romanining shakllanishi, J. Org. Kimyoviy. 68: 3367-3379 (2003)